High energy chemistry number 3 year 1982. What he studies: High energy chemistry

Chemistry of high energies [Electronic resource].- 2017 .- No. 2 .- 84 p. - Access mode: https://website/efd/556147

Individual articles are also available for release:
FEATURES OF THE MOLECULAR-TOPOLOGICAL STRUCTURE OF GAMMA-IRRADIATED POWDER COPOLYMER OF TETRAFLUOROETHYLENE WITH PERFLUOROVINYL PROPYL ETHER / Allayarov (200.00 rubles)
RADIATION POLYMERIZATION OF METHACRYLATES CONTROLLED BY A CHAIN ​​TRANSFER CATALYST / Roshchupkin (200.00 rubles)
GENERATION OF HYDROGEN BY HYDROREACTIVE COMPOSITIONS WITH γ-IRRADIATED ALUMINUM / Milinchuk (200.00 rubles)
RADIATION SYNTHESIS OF TETRAFLUOROETHYLENE TELOMERES IN CHLOROSILANES AND THEIR USE FOR MODIFICATION OF ALUMINOBOROSILICATE GLASS FABRIC / Kichigina (200.00 rubles)
EFFECT OF GAMMA-IRRADIATION AND THERMAL ANNEALING ON THE MOLECULAR-TOPOLOGICAL STRUCTURE OF THE COPOLYMER OF TETRAFLUOROETHYLENE AND PERFLUOROPROPYLVINYL ETHER / Olkhov (200.00 rubles)
SPECTRAL-LUMINESCENT AND QUANTUM-CHEMICAL INVESTIGATION OF ANIONIC FORMS OF 5-FLUORURACIL / Ostakhov (200.00 rubles)
EFFECT OF SUBSTITUTES ON SPECTRAL, LUMINESCENT AND SPECTRAL-KINETIC PROPERTIES OF 2,5-DIARYLIDENE DERIVATIVES OF CYCLOPENTANONE / Zakharova (200.00 rub.)
Effect of Alkanthiols on Fluorescence Twinkling of Colloidal Quantum Dots [email protected]/ Gak (200.00 rubles)
OPTIMIZATION OF THE PROCESS OF PLASMA TREATMENT OF AQUEOUS SOLUTIONS OF SODIUM CHLORIDE / Nikolenko (200.00 rubles)
CONVERSION OF HYDROCARBON GASES IN A BARRIER DISCHARGE IN THE PRESENCE OF WATER / Kudryashov (200.00 rubles)
EXPERIMENTAL STUDY OF GASIFICATION OF TARS IN A METAL MELT WITH CYCLIC SUPPLY OF CARBON-CONTAINING RAW AND OXIDANT TO THE REACTOR / Babaritsky (200.00 rubles)
MODIFICATION OF ULTRA-HIGH-MOLECULAR POLYETHYLENE IN LOW-TEMPERATURE PLASMA (REVIEW) / Gilman (200.00 rubles)
NEW DATA ON THE COMPOSITION OF PRODUCTS OF ULTRASONIC IRRADIATION OF GRAPHITE IN N-METHYLPIRROLIDONE / Shulga (200.00 rub.)
TRIPLET STATES OF BIS-CARBOCYANINE DYE AND ALBUMIN COMPLEXES / Kostyukov (200.00 rubles)

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Economics - politics - culture Theoretical and mathematical physics Theoretical foundations of chemical technology * Probability theory and its applications Thermal physics high temperatures* Proceedings of the V.A. Steklova* Advances in Mathematical Sciences Advances in Modern Biology Advances in Physiological Sciences Physics of the Earth* Physics and Technology of Semiconductors* Physics and chemistry glass* Physics of metals and metal science* Plasma physics* Solid state physics* Physical chemistry of surfaces and protection of materials* Plant physiology* Human physiology* Functional analysis and its applications Chemical physics* Chemistry high energies* Chemistry solid fuel* Cytology* Man Ecology* Economics and mathematical methods Electrochemistry* Energy, Economics, Technology, Ecology Ethnographic Review Entomological Review* Nuclear Physics* * Journal materials are published by Pleiades Publishing English language http://www.naukaran.com The journal publishes original and review articles, brief messages, letters to the editor on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry nanoscale systems, chemistry new atoms, processes and materials for optical information systems, By scientific foundations relevant technologies, as well as a chronicle and book reviews in the field chemistry high energies. magazine is 50 years old CHEMISTRY HIGH ENERGY Volume 51, Issue 2 March - April 2017 ISSN 0023-1193 ISSN 0023-1193 Chemistry high energies, 2017, Volume 51, No. 2 CONTENTS Volume 51, No. 2, 2017 RADIATION CHEMISTRY Peculiarities molecular topological buildings gamma irradiated copolymer powder tetrafluoroethylene with perfluorovinylpropyl ether S. R. Allayarov, Yu. A. Olkhov, N. N. Loginova, I. I. Sadikov, M. Yu. Tashmetov radiation polymerization catalyst-controlled chain transfer V. P. Roshchupkin, M. P. Berezin, D. P. Kiryukhin Hydrogen generation by hydroreactive compositions<...>

Chemistry_high_energy_№2_2017.pdf

CONTENTS Volume 51, Number 2, 2017 RADIATION CHEMISTRY Peculiarities of the molecular topological structure of gamma-irradiated powdered copolymer of tetrafluoroethylene with perfluorovinylpropyl ether S. R. Allayarov, Yu. A. Olkhov, N. N. Loginova, I. I. Sadikov, M. Yu. Tashmetov Radiation polymerization of methacrylates controlled by a chain transfer catalyst V. P. Roshchupkin, M. P. Berezin, D. P. Kiryukhin Hydrogen generation by hydroreaction compositions with γ-irradiated aluminum V. K. Milinchuk, E. R. Klinshpont , V. I. Belozerov Radiation synthesis of tetrafluoroethylene telomers in chlorosilanes and their use for modifying aluminoborosilicate glass fabric G. A. Kichigina, P. P. Kushch, D. P. Kiryukhin Effect of gamma irradiation and thermal annealing on the molecular topological structure of a copolymer of tetrafluoroethylene and perfluoropropylvinyl ether Yu. A. Olkhov, S. R. Allayarov, RS Allayarov, D. A. Dixon Ostakhov, M. V. Sultanbaev, M. Yu. Ovchinnikov, R. R. Kayumova, S. L. Khursan F. S. Zyuzkevich, V. N. Gutrov, G. V. Gavrilova, V. N. Nuriev, S. Z. Vatsadze, V. G. Plotnikov, S. P. Gromov, A. K. Chibisov flickering fluorescence of colloidal quantum dots [email protected] V. Yu. Gak, S. A. Tovstun, M. G. Spirin, S. B. Brichkin, V. F. Razumov PLASMA CHEMISTRY Optimization of the plasma treatment process aqueous solutions sodium chloride N. V. Nikolenko, R. I. Zakharov, A. V. Dubenko, G. V. Moleva, T. N. Avdienko Conversion hydrocarbon gases in a barrier discharge in the presence of water S. V. Kudryashov, A. Yu. Ryabov, A. N. Ocheredko Experimental study of the gasification of tar in a metal melt with cyclic supply of carbon-containing raw materials and an oxidizer to the reactor A. I. Babaritsky, M. B. Bibikov , M. A. Deminsky, S. A. Demkin, S. V. Korobtsev, M. F. Krotov, B. V. Potapkin, R. V. Smirnov, F. N. Chebankov Modification of ultra-high molecular weight polyethylene in low-temperature plasma (Review ) A. B. Gilman, M. S. Piskarev, A. A. Kuznetsov, A. N. Ozerin 147 142 131 137 121 126 116 109 103 99 94 85

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SONOCHEMISTRY New data on the composition of graphite ultrasonic irradiation products in N-methylpyrrolidone Yu. M. Shulga, AS Lobach, FO Milovich, N. Yu. Shulga, DA Kiselev, SA Baskakov PHOTOCHEMISTRY Triplet states of complexes of bis-carbocyanine dye and albumin A. A. Kostyukov, T. D. Nekipelova, A. Sh. Pablo J. Gonçalves, André L. S. Pavanelli, Lucimara P. Ferreira, Andre M. Amado, Y. E. Borisevich, V. A. Kuzmin Conv. oven l. 10.25 arb. kr.-ott. 0.6 thousand. Circulation 52 copies. Law 84 Publication date 03/23/2017 Format 60 H 881/8 Uch.-ed. l. 10.25 Boom. l. 5.1 Free price Founders: Russian Academy of Sciences, Center for Photochemistry RAS Publisher: Russian Academy of Sciences. Nauka Publishing House, 117997, Moscow, Profsoyuznaya st., 90

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The concept of high-energy physics is now quite well known, including to a simple layman, because in recent years many giant projects have been created in this area (primarily the Large Hadron Collider). High-energy physics at the initial level is understandable to many: everyone knows that there is a search for new elementary particles, new elements are synthesized by collisions, for this gigantic installations are built, tunnels tens of kilometers long, and even at the household level it is clear that this is associated with very high energies. What is "high energy chemistry" is known to a much smaller number of people, even in a professional chemical environment. Not because it is something exotic, but because this term has not yet found such a wide application. Although, if you understand its deep essence, everything becomes quite obvious.

1. Thermal reactions

If at the Large Hadron Collider we are talking about the energies that are created by giant generators, about insane discharges that can kill a person, then in high-energy chemistry everything is different. Sunlight entering through a window in a room is already high energy for a chemical system. It is important to determine which criterion is at work here.

How do almost every chemical reaction we know from school get started? The vast majority of reactions are due to thermal energy. Thermal energy is communicated to the system, some vibrational modes are excited, the molecule or parts of the molecule begin to move differently. If you look at it from the point of view of quantum chemistry, then the system gets to a higher vibrational level and behaves there in such a way that the reaction becomes inevitable. There are such terms as "adiabatic" and "non-adiabatic processes" (instead of the second term, you can say "diabatic" so that there is no double negation on a mixture of Russian and Greek), and if thermal reactions are adiabatic, then high-energy chemistry deals with non-adiabatic processes. .

2. Electronically excited state

Thermal reactions are what happens within a single potential energy surface. If we imagine a mountain range, then a thermal reaction is a transition from one valley to another valley through a mountain pass. At the same time, most likely, everything is more profitable in terms of energy in the second valley, roughly speaking (continuing the analogy, we can say that it lies lower). Not so with high energy chemistry. Here we are not on one surface, but we are moving to some other one. This other surface is called the electronically excited state. That is, if we continue the analogy with a mountain pass, we climb the tower, the funicular, and this funicular rides over the mountain pass. Thus, instead of going through the pass on foot, we rush over it. How does this translate into chemical processes? High energies can be communicated, for example, by light, which corresponds to one of the branches of high energy chemistry - photochemistry. Or ionizing radiation, which corresponds to radiation chemistry. In the vast majority of cases, they are higher than something that can be communicated to the system by thermal action. At the same time, from the point of view of physics, these are quite low energies, but if we talk about the excitation of a chemical system, that is, how atoms behave in a molecule, there is a very significant difference here, and due to the fact that we move to another potential surface energy opens up a host of other possibilities. Imagine that there is some kind of insurmountable peak, but if you pass over it, you will be able to get to where we would not have reached on foot. This analogy is very telling here. The fact that other electronically excited states are involved in the system opens the way to new reaction mechanisms. And this is justified both for photochemistry and for radiation chemistry, as well as for the third section of high energy chemistry - plasma chemistry.

3. Chemistry of high energies in everyday life

If carrying out radiation-chemical reactions requires special equipment, sources of ionizing radiation (these include electron beams, gamma radiation, X-rays), then some of the simplest photochemical experiments can be carried out even at home. That is, if you put some bright postcard on the window for a couple of days or a week in the summer, you will see that it fades. This means that a photochemical reaction is taking place: the light is absorbed by the dye on the paper, and processes occur that would not have been carried out if the postcard had simply been lying in a warm place, because the light transfers energy, which is enough to transfer the system to electronically excited state.

4. Photochemical reactions

Photochemical reactions in their primitive form have been known since medieval times, but the nature of these phenomena became finally understood only in the 20th century. Although some quantitative patterns of photochemical reactions were already described in the 19th century, then scientists could only carry out some simple processes, those that can now be carried out in physical chemistry workshops, for example, the reaction of decomposition of hydrogen peroxide. Photochemistry is a gigantic branch of chemistry that is directly related to macromolecular chemistry, since, for example, many polymers can be obtained under the action of light, and to biochemistry, because all people exist thanks to photochemistry, since photosynthesis is a photochemical process.

5. Three branches of high energy chemistry

The concept of "high energy chemistry" should in no case be confused with the concept of "high energy physics". High energy chemistry includes three major branches: photochemistry, radiation chemistry, and plasma chemistry. Despite the fact that the phrase "radiation chemistry" sounds dangerous, radiation chemistry does not directly deal with radioactivity and radionuclides. Chemists simply shine X-rays on something, and because of this, some processes occur, and this does not mean at all that radioactivity appears in the object. The most intuitive branch of high energy chemistry is photochemistry, where reactions are studied under the action of light. This section includes the study of photosynthesis and, for example, what can happen under the influence of light in beer (it is not for nothing that it is stored in dark bottles), or what happens when you break a special luminescent stick in a nightclub, and it starts glow, or the phenomenon that makes film photography possible.

6. Use of high energy chemistry in industry

Processes related to high energy chemistry are already widely used in industry. This includes the production of polymers both by photoinitiation and by radiation-chemical initiation of polymerization reactions, and radiation-chemical water purification - one of the most environmentally friendly methods of purification, and disinfection of products, and a huge number of processes that are associated with photosensitivity. All this can easily be developed further, and the effectiveness of these processes, most likely, will only increase.

Scientometric indicators

Usage

• 6795 Full Text Downloads 2018

  Springer measures the number of downloads of full texts from the SpringerLink platform in accordance with COUNTER (Counting Online Usage of NeTworked Electronic Resources) standards.

• 23 Usage factor 2017/2018

  The usage factor is a value calculated according to the rules recommended by COUNTER. This is the average (median) number of downloads in 2017/18. for all articles published online in the same journal during the same period. The usage factor calculation is based on data that complies with the COUNTER standards on the SpringerLink platform.

Influence

• 0.634 Impact Factor 2018

  Impact factor published by Clarivate Analytics in Journal Citation Reports. Impact factors refer to the previous year.

• 0.59 Source Normalized Impact per Paper (SNIP) 2018

  Source Normalized Impact per Paper (SNIP) measures a journal's contextual citation impact by weighting the citations in each subject group. The contribution of each individual citation is the higher in each specific subject category, the less likely (for reasons of subject content) that such a citation will occur.

• Q4 Quartile: Physical and Theoretical Chemistry 2018

  A set of journals from the same subject category are ranked according to their SJR and divided into 4 groups called quartiles. Q1 (green) combines the journals with the highest scores, Q2 (yellow) - following them, Q3 (orange orange) - the third group in terms of SJR, Q4 (red) - journals with the lowest scores.

• 0.27 SCImago Journal Rank (SJR) 2018

  SCImago Journal Rank (SJR) is a measure of a journal's scientific impact that takes into account the number of citations a journal receives and the rating of citing journals.

• 19 h-index 2018

SCOPE

High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.

Indexing and referencing

Chemical Abstracts Service (CAS), Chimica, Current Contents/Physical, Chemical and Earth Sciences, EBSCO Academic Search, EBSCO Advanced Placement Source, EBSCO Discovery Service, EBSCO Engineering Source, EBSCO Environment, EBSCO STM Source, Gale, Gale Academic OneFile, Gale InfoTrac, Google Scholar, INIS Atomindex, INSPEC, Institute of Scientific and Technical Information of China, Japanese Science and Technology Agency (JST), Journal Citation Reports/Science Edition, Naver, OCLC WorldCat Discovery Service, ProQuest Central, ProQuest Materials Science and Engineering Database, ProQuest SciTech Premium Collection, ProQuest Technology Collection, ProQuest-ExLibris Primo, ProQuest-ExLibris Summon, Reaction Citation Index, Reaxys, SCImago, SCOPUS, Science Citation Index, Science Citation Index Expanded (SciSearch), Semantic Scholar.